The calculated distance (air line) between Villafranca de los Caballeros and Alicante is approximately 172 miles respectively 277 kilometers.
By car or train, the actual journey to Alicante is certainly longer, as only the direct route (as the crow flies) between Villafranca de los Caballeros and Alicante has been calculated here.
Air line (approximately)
277 kilometers
149 nautical miles