The calculated distance (air line) between La Puebla de Almoradiel and Valladolid is approximately 165 miles respectively 266 kilometers.
By car or train, the actual journey to Valladolid is certainly longer, as only the direct route (as the crow flies) between La Puebla de Almoradiel and Valladolid has been calculated here.
Air line (approximately)
266 kilometers
143 nautical miles