The calculated distance (air line) between Villaviciosa de Odón and Valladolid is approximately 99 miles respectively 160 kilometers.
By car or train, the actual journey to Valladolid is certainly longer, as only the direct route (as the crow flies) between Villaviciosa de Odón and Valladolid has been calculated here.
Air line (approximately)
160 kilometers
86 nautical miles