The calculated distance (air line) between Valladolid and Pozuelo de Alarcón is approximately 97 miles respectively 156 kilometers.
By car or train, the actual journey to Pozuelo de Alarcón is certainly longer, as only the direct route (as the crow flies) between Valladolid and Pozuelo de Alarcón has been calculated here.
Air line (approximately)
156 kilometers
84 nautical miles