The calculated distance (air line) between Krasnoarmeyskoye and Tolyatti is approximately 63 miles respectively 101 kilometers.
By car or train, the actual journey to Tolyatti is certainly longer, as only the direct route (as the crow flies) between Krasnoarmeyskoye and Tolyatti has been calculated here.
Air line (approximately)
101 kilometers
55 nautical miles