The calculated distance (air line) between Villanueva del Arzobispo and Alicante is approximately 138 miles respectively 221 kilometers.
By car or train, the actual journey to Alicante is certainly longer, as only the direct route (as the crow flies) between Villanueva del Arzobispo and Alicante has been calculated here.
Air line (approximately)
221 kilometers
119 nautical miles