The calculated distance (air line) between Sant'Ambrogio di Valpollicella and Livorno is approximately 139 miles respectively 223 kilometers.
By car or train, the actual journey to Livorno is certainly longer, as only the direct route (as the crow flies) between Sant'Ambrogio di Valpollicella and Livorno has been calculated here.
Air line (approximately)
223 kilometers
121 nautical miles