The calculated distance (air line) between Villeneuve-lès-Avignon and Toulon is approximately 81 miles respectively 131 kilometers.
By car or train, the actual journey to Toulon is certainly longer, as only the direct route (as the crow flies) between Villeneuve-lès-Avignon and Toulon has been calculated here.
Air line (approximately)
131 kilometers
71 nautical miles