The calculated distance (air line) between Bloemfontein and Phuthaditjhaba is approximately 163 miles respectively 262 kilometers.
By car or train, the actual journey to Phuthaditjhaba is certainly longer, as only the direct route (as the crow flies) between Bloemfontein and Phuthaditjhaba has been calculated here.
Air line (approximately)
262 kilometers
141 nautical miles